Sunday 
 
 
4:00 pm - 8:00 pm 
	
Arrival and Check-in
 
 
						
6:00 pm - 7:00 pm 
	
Dinner
 
 
						
7:30 pm - 7:40 pm 
	
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
 
 
						
7:40 pm - 9:30 pm 
	
Transition Metals in Organic Synthesis 
 
 
 
						
7:40 pm - 7:45 pm 
	
Opening Remarks
 
 
						
7:45 pm - 8:15 pm 
	
"Catalysis with Metal Carbonyl Complexes" 
 
 
 
						
8:15 pm - 8:30 pm 
	
Discussion
 
 
						
8:30 pm - 9:00 pm 
	
"Is Concerted-Metalation Deprotonation (CMD) a Singular C-H Activation Mechanism? Evidence for a Catalyst-Controlled Continuum" 
 
 
 
						
9:00 pm - 9:15 pm 
	
Discussion
 
 
						
9:15 pm - 9:30 pm 
	
General Discussion
 
 
						
	Monday 
 
 
7:30 am - 8:30 am 
	
Breakfast
 
 
						
8:30 am - 9:00 am 
	
Group Photo
 
 
						
9:00 am - 12:30 pm 
	
Catalysis with Inexpensive Metals 
 
 
 
						
9:00 am - 9:30 am 
	
"One or Two Electron Redox? Oxidation-Induced C-H Functionalization and Oxidative Cross-Coupling" 
 
 
 
						
9:30 am - 9:45 am 
	
Discussion
 
 
						
9:45 am - 10:15 am 
	
"A Metallopeptide Nitrite Reductase" 
 
 
 
						
10:15 am - 10:30 am 
	
Discussion
 
 
						
10:30 am - 11:00 am 
	
Coffee Break
 
 
						
11:00 am - 11:30 am 
	
"Catalysis at Metal-Metal Bonds" 
 
 
 
						
11:30 am - 11:45 am 
	
Discussion
 
 
						
11:45 am - 12:15 pm 
	
"Mechanistic Studies of Ti-Catalyzed Nitrene Transfer Reactions as a Platform for Reaction Discovery" 
 
 
 
						
12:15 pm - 12:30 pm 
	
Discussion
 
 
						
12:30 pm - 1:30 pm 
	
Lunch
 
 
						
1:30 pm - 4:00 pm 
	
Free Time
 
 
						
4:00 pm - 6:00 pm 
	
Poster Session 
 
 
						
6:00 pm - 7:00 pm 
	
Dinner
 
 
						
7:30 pm - 9:30 pm 
	
Electrocatalysis for Energy and Synthesis 
 
 
 
						
7:30 pm - 8:00 pm 
	
"Electrocatalytic Ammonia Splitting: Enabling the Renewable Fuel of the Future" 
 
 
 
						
8:00 pm - 8:15 pm 
	
Discussion
 
 
						
8:15 pm - 8:45 pm 
	
"Molecular Catalysis of Electrochemical Reactions: Tools for Mechanism Analysis, Catalyst Optimization and Selectivity Control" 
 
 
 
						
8:45 pm - 9:00 pm 
	
Discussion
 
 
						
9:00 pm - 9:10 pm 
	
"Hydrogen Evolution by the Co-Mabiq Complex: The Relevance of Ligand Non-Innocence to Reactivity" 
 
 
 
						
9:10 pm - 9:15 pm 
	
Discussion
 
 
						
9:15 pm - 9:25 pm 
	
"Mimicking the Mittasch Catalyst with Macrocycle-Supported Cluster Complexes" 
 
 
 
						
9:25 pm - 9:30 pm 
	
Discussion
 
 
						
	Tuesday 
 
 
7:30 am - 8:30 am 
	
Breakfast
 
 
						
9:00 am - 12:30 pm 
	
Mechanisms on, in and for Materials 
 
 
 
						
9:00 am - 9:30 am 
	
"C-H Activation and Hydrogen/Deuterium (H/D) Exchange: Mechanistic Insight on Heterogeneous Catalysts" 
 
 
 
						
9:30 am - 9:45 am 
	
Discussion
 
 
						
9:45 am - 10:15 am 
	
"Taking the Molecular to the Macromolecular: Inorganic Electron Transfer Catalysis in Metal Organic Frameworks" 
 
 
 
						
10:15 am - 10:30 am 
	
Discussion
 
 
						
10:30 am - 11:00 am 
	
Coffee Break
 
 
						
11:00 am - 11:30 am 
	
"Solid-State Molecular Organometallic Chemistry: The Importance of the Anion Microenvironment in Synthesis and Catalysis" 
 
 
 
						
11:30 am - 11:45 am 
	
Discussion
 
 
						
11:45 am - 12:15 pm 
	
"Mechanistic Insights into Redox-Switchable Polymerization Catalysis" 
 
 
 
						
12:15 pm - 12:30 pm 
	
Discussion
 
 
						
12:30 pm - 1:30 pm 
	
Lunch
 
 
						
1:30 pm - 4:00 pm 
	
Free Time
 
 
						
4:00 pm - 6:00 pm 
	
Poster Session 
 
 
						
6:00 pm - 7:00 pm 
	
Dinner
 
 
						
7:30 pm - 9:30 pm 
	
Transformations in the f-Block 
 
 
 
						
7:30 pm - 8:00 pm 
	
"Many-Electron Reductive Activation and Functionalization of Small Molecules with Dinuclear 5f-Organometallics" 
 
 
 
						
8:00 pm - 8:15 pm 
	
Discussion
 
 
						
8:15 pm - 8:45 pm 
	
"Follow the Thread: Unraveling the Mechanism of Substrate Reduction by Samarium(II)-Proton Donor Complexes" 
 
 
 
						
8:45 pm - 9:00 pm 
	
Discussion
 
 
						
9:00 pm - 9:10 pm 
	
"Molecular Electrocatalysts for Reductive CO2  and O2  Activation" 
 
 
 
						
9:10 pm - 9:15 pm 
	
Discussion
 
 
						
9:15 pm - 9:25 pm 
	
"Oxidative Reactivity of Nitrite at Dicopper Center" 
 
 
 
						
9:25 pm - 9:30 pm 
	
Discussion
 
 
						
	Wednesday 
 
 
7:30 am - 8:30 am 
	
Breakfast
 
 
						
9:00 am - 12:30 pm 
	
Computational and Spectroscopic Techniques to Probe Mechanism 
 
 
 
						
9:00 am - 9:30 am 
	
"The Water Oxidation Reaction in Natural Photosynthesis" 
 
 
 
						
9:30 am - 9:45 am 
	
Discussion
 
 
						
9:45 am - 10:15 am 
	
"Electronic Structures of Late Metal Complexes in Unusual Formal Oxidation States" 
 
 
 
						
10:15 am - 10:30 am 
	
Discussion
 
 
						
10:30 am - 11:00 am 
	
Coffee Break
 
 
						
11:00 am - 11:30 am 
	
"Fundamental Properties of C-H Bonds: Relevance to Catalytic Hydrocarbon Functionalization" 
 
 
 
						
11:30 am - 11:45 am 
	
Discussion
 
 
						
11:45 am - 12:15 pm 
	
"In Dialogue with Nature: Molecules, Quantum Mechanics, Spectroscopy and Reaction Mechanisms" 
 
 
 
						
12:15 pm - 12:30 pm 
	
Discussion
 
 
						
12:30 pm - 1:30 pm 
	
Lunch
 
 
						
1:30 pm - 4:00 pm 
	
Free Time
 
 
						
4:00 pm - 6:00 pm 
	
Poster Session 
 
 
						
6:00 pm - 7:00 pm 
	
Dinner
 
 
						
7:00 pm - 7:30 pm 
	
Business Meeting 
Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair 
 
 
						
7:30 pm - 9:30 pm 
	
Mechanisms in the Second Sphere 
 
 
 
						
7:30 pm - 8:00 pm 
	
"Roles of Pyridinol-Type Ligands for CO2  Reduction and Hydrogenation" 
 
 
 
						
8:00 pm - 8:15 pm 
	
Discussion
 
 
						
8:15 pm - 8:45 pm 
	
"Transition Metal Catalysts for N2  Reduction and NH3  Oxidation: Strategies for Making and Breaking N=N and N-H Bonds" 
 
 
 
						
8:45 pm - 9:00 pm 
	
Discussion
 
 
						
9:00 pm - 9:10 pm 
	
"Understanding the Selectivity of Oxygen Activation by Iron-Porphyrin Catalysts" 
 
 
 
						
9:10 pm - 9:15 pm 
	
Discussion
 
 
						
9:15 pm - 9:25 pm 
	
"Stabilization and Reactivity of Low-Valent Copper on Titania Aerogels" 
 
 
 
						
9:25 pm - 9:30 pm 
	
Discussion
 
 
						
	Thursday 
 
 
7:30 am - 8:30 am 
	
Breakfast
 
 
						
9:00 am - 12:30 pm 
	
Uncovering Bioinorganic Reaction Mechanisms 
 
 
 
						
9:00 am - 9:30 am 
	
"Bioorganometallic Chemistry Within a Model Nickel Enzyme" 
 
 
 
						
9:30 am - 9:45 am 
	
Discussion
 
 
						
9:45 am - 10:15 am 
	
"Insights into the Oxidative Mechanism of a New Class of Copper Enzymes: Lytic Polysaccharide Monooxygenases" 
 
 
 
						
10:15 am - 10:30 am 
	
Discussion
 
 
						
10:30 am - 11:00 am 
	
Coffee Break
 
 
						
11:00 am - 11:30 am 
	
"Defining a Substrate-Binding Site in Nitrogenases: Implications for the Mechanism of Dinitrogen Reduction" 
 
 
 
						
11:30 am - 11:45 am 
	
Discussion
 
 
						
11:45 am - 12:15 pm 
	
"Synthetic Fe Nitrogenases and How They Work" 
 
 
 
						
12:15 pm - 12:30 pm 
	
Discussion
 
 
						
12:30 pm - 1:30 pm 
	
Lunch
 
 
						
1:30 pm - 4:00 pm 
	
Free Time
 
 
						
4:00 pm - 6:00 pm 
	
Poster Session 
 
 
						
6:00 pm - 7:00 pm 
	
Dinner
 
 
						
7:30 pm - 9:30 pm 
	
Keynote Session: Enabling Mechanisms for Grand Chemical Challenges 
 
 
 
						
7:30 pm - 7:40 pm 
	
"Isolation, Characterization and Basicity Driven C-H Activation Reactivity of a Terminal Co(III)-Oxo Complex" 
 
 
 
						
7:40 pm - 7:45 pm 
	
Discussion
 
 
						
7:45 pm - 7:55 pm 
	
"Understanding Catalyst Structural Effects on the Ring-Opening Transesterification Polymerization of Cyclic Esters" 
 
 
 
						
7:55 pm - 8:00 pm 
	
Discussion
 
 
						
8:00 pm - 8:10 pm 
	
"Synthesis and Reactivity of M-Alkyl, M-Hydroxo and M-Amido Complexes Supported by a Dianionic Pentadentate Ligand" 
 
 
 
						
8:10 pm - 8:15 pm 
	
Discussion
 
 
						
8:15 pm - 9:00 pm 
	
"Olefin Metathesis: The Gift that Keeps on Giving" 
 
 
 
						
9:00 pm - 9:15 pm 
	
Discussion
 
 
						
9:15 pm - 9:30 pm 
	
Closing Remarks
 
 
						
	Friday 
 
 
7:30 am - 8:30 am 
	
Breakfast
 
 
						
9:00 am 
	
Departure