Sunday
4:00 pm - 8:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
7:40 pm - 9:30 pm
Transition Metals in Organic Synthesis
7:40 pm - 7:45 pm
Opening Remarks
7:45 pm - 8:15 pm
"Catalysis with Metal Carbonyl Complexes"
8:15 pm - 8:30 pm
Discussion
8:30 pm - 9:00 pm
"Is Concerted-Metalation Deprotonation (CMD) a Singular C-H Activation Mechanism? Evidence for a Catalyst-Controlled Continuum"
9:00 pm - 9:15 pm
Discussion
9:15 pm - 9:30 pm
General Discussion
Monday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Catalysis with Inexpensive Metals
9:00 am - 9:30 am
"One or Two Electron Redox? Oxidation-Induced C-H Functionalization and Oxidative Cross-Coupling"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"A Metallopeptide Nitrite Reductase"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Catalysis at Metal-Metal Bonds"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Mechanistic Studies of Ti-Catalyzed Nitrene Transfer Reactions as a Platform for Reaction Discovery"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Electrocatalysis for Energy and Synthesis
7:30 pm - 8:00 pm
"Electrocatalytic Ammonia Splitting: Enabling the Renewable Fuel of the Future"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Molecular Catalysis of Electrochemical Reactions: Tools for Mechanism Analysis, Catalyst Optimization and Selectivity Control"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Hydrogen Evolution by the Co-Mabiq Complex: The Relevance of Ligand Non-Innocence to Reactivity"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Mimicking the Mittasch Catalyst with Macrocycle-Supported Cluster Complexes"
9:25 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Mechanisms on, in and for Materials
9:00 am - 9:30 am
"C-H Activation and Hydrogen/Deuterium (H/D) Exchange: Mechanistic Insight on Heterogeneous Catalysts"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Taking the Molecular to the Macromolecular: Inorganic Electron Transfer Catalysis in Metal Organic Frameworks"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Solid-State Molecular Organometallic Chemistry: The Importance of the Anion Microenvironment in Synthesis and Catalysis"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Mechanistic Insights into Redox-Switchable Polymerization Catalysis"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Transformations in the f-Block
7:30 pm - 8:00 pm
"Many-Electron Reductive Activation and Functionalization of Small Molecules with Dinuclear 5f-Organometallics"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Follow the Thread: Unraveling the Mechanism of Substrate Reduction by Samarium(II)-Proton Donor Complexes"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Molecular Electrocatalysts for Reductive CO2 and O2 Activation"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Oxidative Reactivity of Nitrite at Dicopper Center"
9:25 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Computational and Spectroscopic Techniques to Probe Mechanism
9:00 am - 9:30 am
"The Water Oxidation Reaction in Natural Photosynthesis"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Electronic Structures of Late Metal Complexes in Unusual Formal Oxidation States"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Fundamental Properties of C-H Bonds: Relevance to Catalytic Hydrocarbon Functionalization"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"In Dialogue with Nature: Molecules, Quantum Mechanics, Spectroscopy and Reaction Mechanisms"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:00 pm - 7:30 pm
Business Meeting
Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair
7:30 pm - 9:30 pm
Mechanisms in the Second Sphere
7:30 pm - 8:00 pm
"Roles of Pyridinol-Type Ligands for CO2 Reduction and Hydrogenation"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Transition Metal Catalysts for N2 Reduction and NH3 Oxidation: Strategies for Making and Breaking N=N and N-H Bonds"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Understanding the Selectivity of Oxygen Activation by Iron-Porphyrin Catalysts"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Stabilization and Reactivity of Low-Valent Copper on Titania Aerogels"
9:25 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Uncovering Bioinorganic Reaction Mechanisms
9:00 am - 9:30 am
"Bioorganometallic Chemistry Within a Model Nickel Enzyme"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Insights into the Oxidative Mechanism of a New Class of Copper Enzymes: Lytic Polysaccharide Monooxygenases"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Defining a Substrate-Binding Site in Nitrogenases: Implications for the Mechanism of Dinitrogen Reduction"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Synthetic Fe Nitrogenases and How They Work"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Keynote Session: Enabling Mechanisms for Grand Chemical Challenges
7:30 pm - 7:40 pm
"Isolation, Characterization and Basicity Driven C-H Activation Reactivity of a Terminal Co(III)-Oxo Complex"
7:40 pm - 7:45 pm
Discussion
7:45 pm - 7:55 pm
"Understanding Catalyst Structural Effects on the Ring-Opening Transesterification Polymerization of Cyclic Esters"
7:55 pm - 8:00 pm
Discussion
8:00 pm - 8:10 pm
"Synthesis and Reactivity of M-Alkyl, M-Hydroxo and M-Amido Complexes Supported by a Dianionic Pentadentate Ligand"
8:10 pm - 8:15 pm
Discussion
8:15 pm - 9:00 pm
"Olefin Metathesis: The Gift that Keeps on Giving"
9:00 pm - 9:15 pm
Discussion
9:15 pm - 9:30 pm
Closing Remarks
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure