Sunday
2:00 pm - 9:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
7:40 pm - 9:30 pm
Organometallics in Polymer Chemistry
7:40 pm - 7:50 pm
Opening Remarks
7:50 pm - 8:20 pm
"Organometallic Mediated Radical Polymerization (OMRP): The Importance of Making and Breaking Metal-Carbon Bonds"
8:20 pm - 8:35 pm
Discussion
8:35 pm - 9:05 pm
"Using Dynamic and Switchable Polymerization Catalysts to Diversify a Degradable Polymer"
9:05 pm - 9:20 pm
Discussion
9:20 pm - 9:30 pm
General Discussion
Monday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Transition Metal Based Organometallics in Synthesis and Catalysis
9:00 am - 9:30 am
"Intermediates and Mechanism in Iron Catalyzed C-C Bond Formation"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Catalytic Hydrogenation of Carboxylic Acids Using Low- and High-Valent Transition Metal Complexes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Preparation and Reactivity of Phosphine-Substituted Bis(imino)pyridine and Diimine Molybdenum Compounds"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"On the Mechanism of Organo-Platinum Deposition: Effects of Synthesis Techniques on Active Site Nuclearities and Catalytic Nitroaryl Hydrogenation Selectivity"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Computational Chemistry and Reaction Mechanisms
7:30 pm - 8:00 pm
"Radical Pathways in Organometallic Chemistry: A Mechanistic Picture"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
"On the Significance of the Energy Representation for Catalytic Cycles. Simpler, Physically Correct, and More Elegant"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
"Are There Any Reasons to Study Reaction Mechanisms?"
9:20 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Energy and Sustainability
9:00 am - 9:30 am
"Hydrodeoxygenation of Biomass Derived Sugars and Sugar Condensates into Value Added Chemicals and Fuels"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Making and Breaking NH and NN Bonds with Mo and Fe Complexes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"C-H Bond Formation with CO2 : Insights on Selectivity and Mechanism from Molecular Iron Electrocatalysts"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Using Ligands to Optimize the Form and Function of Solar-Relevant Semiconductor Nanocrystals"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
New Reactivity and Transformations
7:30 pm - 8:00 pm
"Chromium-Catalyzed Ethylene Tetramerization Using Phospholane-Based Ligands"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
"New Catalytic Architectures for Acceptorless Dehydrogenation"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:05 pm
"Catalytic Photoredox C-C and C-N Cross-Couplings"
9:05 pm - 9:10 pm
Discussion
9:10 pm - 9:25 pm
"It Is Not Just up to the Substrate: Palladium(0) Cyclizes Nazarov Substrates Through Intramolecular Allylic Alkylation"
9:25 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Early Metal and f-Block Chemistry
9:00 am - 9:30 am
"Molecular Hydrides of Very Early Metals"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Activation and Functionalization of Small Molecules by Multimetallic Uranium Complexes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Recent Advances in Triamido-Supported Actinide-Ligand Multiple Bonding"
11:30 am - 11:45 am
Discussion
11:45 am - 12:00 pm
"What Does the Revised Mechanism of the Noyori Hydrogenation Reaction Mean for Future Catalyst Design?"
12:00 pm - 12:05 pm
Discussion
12:05 pm - 12:20 pm
"Thorium Redox Chemistry and a New Way to Measure Covalency by Pulsed EPR Spectroscopy"
12:20 pm - 12:25 pm
Discussion
12:25 pm - 12:30 pm
General Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:00 pm - 7:30 pm
Business Meeting
Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair
7:30 pm - 9:30 pm
7:30 pm - 8:00 pm
"Stable Carbenes and Related Species as Powerful Tools in Organometallic Chemistry"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
"Base-Metal Enantioselective Catalysts with Chiral P/N Macrocyclic and Pincer Ligands"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
"Small Molecule Activation Across a Ti=Ti Double Bond"
9:20 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Main Group Organometallic Chemistry
9:00 am - 9:30 am
"C-H Borylation: Will the Road Go on Forever?"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Towards a Paradigm Shift in Main Group Polar Organometallic Chemistry"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Applications of FLP and Lewis Acid Catalysis"
11:30 am - 11:45 am
Discussion
11:45 am - 12:00 pm
"Ambireactive Boron Based Donor Groups in Iron Complexes: Enabling Different Catalytic Processes by Variation of Temperature and Metal Oxidation State"
12:00 pm - 12:05 pm
Discussion
12:05 pm - 12:20 pm
"Redox Active Boranes as Ligands and Platforms for Small Molecule Activation"
12:20 pm - 12:25 pm
Discussion
12:25 pm - 12:30 pm
General Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
New Chemistries from Old Elements
7:30 pm - 8:10 pm
"Organometallic Chemistry of Nickel(III) and Nickel(IV)"
8:10 pm - 8:25 pm
Discussion
8:25 pm - 9:05 pm
"Recent Adventures in the First Row of the Transition Elements"
9:05 pm - 9:20 pm
Discussion
9:20 pm - 9:30 pm
Closing Remarks
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure